The scalability and stability of MOF-based

The gap

Evidence profile

Sourced from the stated research gap and future-work section and limitations section and future work of the source papers, classified as general, drawn from work published between 2024 and 2026, spanning 5 journals. Those papers have been cited 283 times in total.

Supporting evidence — 8 representative gaps

• Dual metallosalen ligands in covalent organic frameworks: structures and electronic properties of TM2C22H18N4O2 (TM = Sc-Zn, Y-Cd) (2026) · Structural Chemistry · doi

  The study identifies a gap in the understanding of the influence of transition metal choice on framework properties. The study identifies a need for the rational design of salen-based M-COFs for high-performance electrocatalysis.

  generalstated research gap
  Keywords: study identifies gap understanding influence transition metal choice
• Indium-based Metal Organic Frameworks (In-MOFs) for Electrochemical Reduction of Carbon Dioxide to Formate (2026) · International Journal of Pure and Applied Chemistry · doi

  The need for highly active, selective, and cost-effective electrocatalysts for large-scale industrial CO2 utilization. The lack of understanding of the relationship between ligand structure and catalyst morphology.

  generalstated research gap
  Keywords: need highly active selective cost-effective electrocatalysts large-scale industrial
• Recent advances and future perspectives of metal-organic frameworks as efficient electrocatalysts for CO2 reduction (2024) · Science China Materials · cited 48× · doi

  Further research is needed to improve the scalability and stability of MOF-based electrocatalysts. The development of new MOF-based electrocatalysts with improved electrocatalytic performance is necessary.

  generalfuture-work section
  Keywords: further research needed improve scalability stability mof-based electrocatalysts
• Recent advances and future perspectives of metal-organic frameworks as efficient electrocatalysts for CO2 reduction (2024) · Science China Materials · cited 48× · doi

  The scalability and stability of MOF-based electrocatalysts need to be improved. The electrocatalytic performance of MOFs can be affected by their structure, composition, and coordination environment.

  generallimitations section
  Keywords: scalability stability mof-based electrocatalysts need improved electrocatalytic performance
• Dithiine-linked metalphthalocyanine framework with undulated layers for highly efficient and stable H2O2 electroproduction (2024) · Nature Communications · cited 139× · doi

  The realization of stable and industrial-level H2O2 electroproduction faces great challenges due to the easy decomposition of H2O2. There is a need for high-performance and low-cost electrocatalysts for H2O2 electrosynthesis. The study addresses the gap by developing a novel CoPc-S-COF framework with an undulated layered structure and increased electron density of the Co center.

  generalstated research gap
  Keywords: realization stable industrial-level h2o2 electroproduction faces great challenges
• Recent advances and future perspectives of metal-organic frameworks as efficient electrocatalysts for CO2 reduction (2024) · Science China Materials · cited 48× · doi

  A considerable number of MOFs have been identified as highly versatile electrocatalytic CO2RR. Recent advancements have introduced a range of innovative strategies to enhance the electrocatalytic performance of MOFs in CO2RR. candidates for These strategies include the design of MOFs with optimized structural features to increase the density of active sites and improve electron and ion transport. Additionally, the incorporation of functionalized linkers or metal nodes has been explored to elevate catalytic activity. Hybrid materials combining MOFs with other catalysts or conductive materials represent another promising approach. Moreover, advanced synthesis techniques and post-synthesis modifications are employed to fine-tune MOF properties for improved CO2 reduction performance. Collectively, these methods aim to enhance the efficiency and selectivity of CO2 conversion into valuable products, addressing key challenges in the field of electrocatalysis.

  generalfuture workevidence 5/5
  Keywords: mofs electrocatalytic recent strategies enhance performance materials synthesis considerable number identified highly versatile advancements introduced
• Bimetallic Cu–Ce Composites of Metal-Organic Frameworks: Synthesis, Characterization, and CO Oxidation Activity (2026) · Proceedings of the National Academy of Sciences, India Section A: Physical Sciences · doi

  Limited work has been reported on binary metal modified MOFs. There is a need for alternative catalysts for CO oxidation. The design of MOF-based catalysts for CO oxidation is an area of ongoing research.

  generalstated research gapevidence 5/5
  Keywords: limited work has been reported binary metal modified
• Bimetallic Cu–Ce Composites of Metal-Organic Frameworks: Synthesis, Characterization, and CO Oxidation Activity (2026) · Proceedings of the National Academy of Sciences, India Section A: Physical Sciences · doi

  Further modification of the structural properties of the bi-metallic Cu-Ce MOF to improve catalytic activity. Investigation of the use of MOF-based catalysts for other oxidation reactions. Development of new MOF-based catalysts with improved performance and stability.

  generalfuture-work sectionevidence 5/5
  Keywords: further modification structural properties bi-metallic cu-ce mof improve

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