Open research questions in Advanced battery technologies research
39 unresolved questions extracted from the limitations and future-work sections of 739 Advanced battery technologies research papers in our library. Each links back to the study that raised it.
What the literature leaves open
Aqueous ZIBs have garnered widespread attention due to their unique advantages of high safety, low cost, good cycling stability, and environmental sustainability, offering strong commercialization prospects. However, ZIBs are https://doi.org/10.1007/s40820-026-02301-w © The authors Nano-Micro Lett.
Design Strategies Toward Zinc Anodes with High Utilization Rate for Practical Aqueous Zinc-Ion Batteries · 2026 · DOIwork identifies interfacial mechanical adaptivity as a critical yet underappreciated design parameter for metal anodes operating under extreme conditions. The concepts presented here are not limited to zinc systems and offer a general strategy for developing durable, high-power metal-based energy storage.
A mechanically adaptive spider-web-like interphase enables secondlevel ultrafast and durable zinc metal batteries · 2026 · DOISummary of key advances HEs have emerged as a promising platform for addressing the two intertwined challenges in ZIBs: polyiodide shuttling at the cathode and Zn dendrite growth/corrosion at the anode. This review has systematically summarized the design principles and working mechanisms of HEs in ZIBs. For single-component HEs, charge-regulation strategies (e.g., sulfonate-functionalized networks) electrostatically repel polyiodides while guiding uniform Zn2+ deposition, whereas chemically interactive hydrogels (e.g., zwitterionic networks) anchor polyiodides via cationic groups and regulate Zn2+ flux through anionic groups.
Advances and challenges of hydrogel electrolytes for rechargeable zinc-iodine batteries · 2026 · DOIThe cost, manufacturability, and scalability of additional multifunctional zinc-ion capacitor components (substrates, encapsulation layers) have not been systematically evaluated. Design strategies that minimize device costs while maintaining performance in these integrated systems require investigation toward grid-scale mass production.
Green and scalable preparation methods for zinc-ion capacitor materials, particularly MXenes, are urgently needed to address current industrial scalability barriers. Current MXene synthesis requires high-concentration acidic environments with low yield and generates costly, environmentally hazardous acid waste, requiring development of alternative synthesis routes.
No standardized evaluation method exists for zinc-ion capacitor electrodes and prototype cells, making cross-comparison of electrochemical properties difficult across flexible and electrochromic ZIC systems. A comprehensive standardization protocol must specify loading density, active material components, electrode area, and key electrochemical performance parameters.
Long-term cycling stability of multifunctional zinc-ion capacitors under operating conditions shows only several hundred cycles achieved in working state, far below practical application requirements. The degradation mechanisms under operating conditions remain underexplored and must be systematically characterized through extended cycling studies.
For integrated electrochemical-storage systems like electrochromic zinc-ion capacitors (ECZ-ICs), high mass loading negatively affects electrochemical capacitor performance. The trade-off between electrochemical performance and energy storage performance in these multifunctional systems requires quantitative investigation to establish optimal loading thresholds.
N/P ratios and areal/volumetric energy densities of zinc-ion capacitors remain far from practical application requirements. Specific targets for N/P ratio optimization, areal energy density thresholds, and volumetric energy density benchmarks need to be established through systematic electrode design and electrolyte formulation studies.
However, the mechanism of HER related to solvation chemistry remains elusive, especially the time-dependent dynamic evolution of the hydrogen bond (H-bond) under an electric field.
Unlocking Dynamic Solvation Chemistry and Hydrogen Evolution Mechanism in Aqueous Zinc Batteries · 2024 · DOIFurthermore, future research should focus on revealing atomic-scale mechanisms through advanced in situ characterization and theoretical calculations, enhancing rate-performance by facilitating ion/electron diffusion, promoting cycling stability by developing highly stable cathodes and refining interface engineering, and scaling up vanadium-based cathodes for practical ZIB applications.
Vanadium-Based Cathodes for Aqueous Zinc-Ion Batteries: Mechanisms, Challenges, and Strategies · 2024 · DOIHypervalent organoiodine compounds have been extensively utilized in organic synthesis, yet their electrochemical properties remain unexplored despite their theoretically high redox potential compared with inorganic iodine, which primarily relies on the I–/I0 redox couple in battery applications.
However, despite the (002) plane's lower surface energy compared to other facets, it remains unclear why this plane does not dominate zinc crystal faces during electrodeposition under normal conditions.
Adjusting Interface Dynamics: A New Insight into the Role of Electrolyte Additive in Facilitating Highly Reversible (002)‐Textured Zinc Anode at High Current and Areal Densities · 2024 · DOIThe charge storage kinetics analysis relies on the Dunn's method for separating capacitive and diffusion-controlled contributions, but experimental validation of these calculated contributions is not explicitly discussed.
Phosphorus-activated carboxyl small molecule positive electrode for high specific capacity and long-life iron-organic batteries · 2026 · DOITremendous progress has been achieved to circumvent these issues in recent years, though a comprehensive review article for both entry-level and experienced researchers is still lacking up to date.
Despite substantial advancements in ZIBs, a comprehensive evaluation of critical parameters impacting their practical energy density ( E practical ) and calendar life is lacking.
Zinc ion Batteries: Bridging the Gap from Academia to Industry for Grid‐Scale Energy Storage · 2024 · DOIWhile diatomic catalysts (DACs) have demonstrated superior performance in various catalytic reactions due to their ability to facilitate synergistic charge interactions, their application in AZIBs remains unexplored.
Diatomic Catalysts for Aqueous Zinc‐Iodine Batteries: Mechanistic Insights and Design Strategies · 2024 · DOI
Most-cited papers in Advanced battery technologies research
- Inhibition of Vanadium Cathodes Dissolution in Aqueous Zn‐Ion Batteries · Advanced Materials · 2024 · 302 citations
- A weakly solvating electrolyte towards practical rechargeable aqueous zinc-ion batteries · Nature Communications · 2024 · 278 citations
- Unlocking Dynamic Solvation Chemistry and Hydrogen Evolution Mechanism in Aqueous Zinc Batteries · Journal of the American Chemical Society · 2024 · 250 citations
- Low-current-density stability of vanadium-based cathodes for aqueous zinc-ion batteries · Science Bulletin · 2024 · 235 citations
- Oxygen Reduction Kinetics of Fe–N–C Single Atom Catalysts Boosted by Pyridinic N Vacancy for Temperature-Adaptive Zn–Air Batteries · Journal of the American Chemical Society · 2024 · 224 citations
- Tandem Chemistry with Janus Mesopores Accelerator for Efficient Aqueous Batteries · Journal of the American Chemical Society · 2024 · 217 citations
- Janus Binder Chemistry for Synchronous Enhancement of Iodine Species Adsorption and Redox Kinetics toward Sustainable Aqueous Zn–I<sub>2</sub> Batteries · Journal of the American Chemical Society · 2024 · 216 citations
- An extended substrate screening strategy enabling a low lattice mismatch for highly reversible zinc anodes · Nature Communications · 2024 · 210 citations
- Confining Iodine into Metal‐Organic Framework Derived Metal‐Nitrogen‐Carbon for Long‐Life Aqueous Zinc‐Iodine Batteries · Advanced Materials · 2024 · 210 citations
- Steric‐hindrance Effect Tuned Ion Solvation Enabling High Performance Aqueous Zinc Ion Batteries · Angewandte Chemie International Edition · 2024 · 208 citations
Most recent work
- Emerging organic cathodes and design strategies for aqueous zinc–organic batteries · eScience · 2026
- Zinc-compound iodine battery chemistry with dual functional oxalate-based electrolyte · Advanced Powder Materials · 2026
- Integrated design of wearable aqueous zinc-ion batteries: From energy autonomy to intelligent sensing · Nano Research Energy · 2026
- Alkyne−Functionalized Covalent Organic Frameworks for Suppressing Polyiodide Shuttle Effect in Aqueous Zinc−Iodine Batteries · ACS Sustainable Chemistry & Engineering · 2026
- Synergistic Interface‐Bulk Regulation of Biopolymer Electrolytes for Advanced Zn‐Iodine Batteries With Four‐Electron I <sup>−</sup> /I <sup>0</sup> /I <sup>+</sup> Conversion · Angewandte Chemie International Edition · 2026
- Phosphorus-activated carboxyl small molecule positive electrode for high specific capacity and long-life iron-organic batteries · Nature Communications · 2026
- Rational Integration of Electron-Positive Linkages into Covalent Organic Framework Electrode for High-Performance Aqueous Zinc-Ion Batteries · ACS Sustainable Chemistry & Engineering · 2026
- Reshaping static aqueous Zn─Br battery chemistry without liquid Br <sub>2</sub> for intrinsic safety and cycle durability · Science Advances · 2026
- High‐Energy‐Density Redox Flow Batteries: Mechanisms, Design Strategies, and Recent Progress · Chemistry – A European Journal · 2026
- Data‐Driven Cation Engineering Guides Electrolyte Design for Sustainable Aqueous Zinc Battery Chemistries · Advanced Materials · 2026
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