Open research questions in CO2 Reduction Techniques and Catalysts
263 gap statements mined from CO2 Reduction Techniques and Catalysts papers in our 7.9M-paper local library, which holds 4,040 papers on the topic — drawn mostly from each paper's own stated research gap, future-work, challenge and limitation notes, and its abstract. The ones listed below are a selection still marked open; each names the study that raised it, with a DOI link where the paper has one.
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What the literature leaves open
The active phase for CO production via the CO2 RR on Pd-based catalysts is unknown. The relationship between the Faradaic efficiency of CO and the hydride stoichiometry of in situ-generated PdHx is not well understood.
To this day, success in producing significant amounts of multicarbon products is limited to a single catalyst, copper, complicating optimization on the catalyst side.
Electrocatalysts Beyond Copper for CO 2 Reduction to Multicarbon Products From Systematic First Principle‐Based Screening · 2026 · DOIWe conclude that the SERS signature, while it can be exceptionally useful, alone is insufficient to establish a rigorous, quantitative correlation between the surface coverage or density of species and the production rates of target products required for a clear structure-activity relationship.
What can Raman spectroscopy really say about the adsorbed CO on roughened Cu electrodes in CO 2 electroreduction conditions? · 2026 · DOIThe electrochemical conversion of CO 2 into carbon nanotubes (CNTs) using molten salt electrolysis is a promising route for carbon capture and utilization, yet the role of anode surface chemistry in governing CNT growth remains poorly understood.
Anode Surface Engineering for Tunable Carbon Nanotube Growth via Integrated Carbon Capture and Conversion in Low‐Cost Molten Carbonates · 2026 · DOIAlthough O, Cl, and Br axial coordination has been explored, fluorine coordination in Ni-based SACs remains unclear.
An Axially Fluorine-Coordinated Ni Single-Atom Catalyst for Highly Efficient CO2 Electrocatalytic Reduction · 2026 · DOIFrom the predictions of both the models, it is evident that CO‐producing catalysts could be further explored for the deeper reduction of CO 2 by the exploration of other conditions, which has not been explored thus far.
Unveiling Catalytic Design Principles for C 2 Product Formation in CO 2 Electroreduction via Machine Learning · 2026 · DOIIncorporating gold (Au) into copper (Cu)-based electrocatalysts effectively enhances the conversion of CO into multicarbon products, yet the fundamental role of Au remains elusive due to limited mechanistic insight.
Deciphering the Role of Au in CO Reduction on Cu: From Atomic Sites to a Stabilized Proton-Transfer Interface · 2026 · DOIWhile elevated pressures improve CO 2 R performance, differential pressure operation above 10 bar between cathode and anode remains underexplored.
Differential pressure CO2 electrolysis opens the way for direct coupling to industrial processes · 2025 · DOIAmong the various strategies chemists are adopting from enzymatic active sites—particularly those involved in CO 2 activation, the role of electrostatic effects stands out as a promising yet underexplored area.
Enhanced CO 2 Electroreduction Through Electrostatic Functionalization of Iron Porphyrin · 2025 · DOIThe hydrophilic porous membrane is sparse and nonpolar, which are features opposite to those seen in the anion-exchange membranes commonly used as the diaphragm in CO2 electrolysis cells.
Development of High‐Performance Zero‐Gap Carbon Dioxide Electrolysis Cells Using a Hydrophilic Porous Membrane · 2025 · DOIHowever, the precise reaction pathways toward CO and HCOOH remain unclear, and the competition between these pathways often leads to low product selectivity.
Recent experiment revealed single Pd atom anchored on graphene exhibits high activity for CO2 electroreduction to syngas, yet the origin of activity and controllable CO/H2 ratios, especially the exact Pd coordination structure, remains elusive.
Revealing the Origin of Graphene Anchored Single Palladium Atom for Electrochemical CO2 Reduction to Syngas with Tunable CO/H2 Ratios · 2024 · DOIThe need to enhance Faradaic efficiency to reduce energy consumption. The requirement for low-cost power and improved electrolyzer performance to decrease the total cost.
Techno-Economic Assessment of Electrochemical CO2 Reduction to Ethylene: A Cu10–Sn Catalyst Case Study and Performance Targets · 2026 · DOIHowever, how different types of Re elements affect the key C–C coupling steps remains unclear, and as a result, RE–Cu dual‐site catalysts often face challenges due to the lack of definitive design guidelines.
CO Adsorption Energy Match at Dual Sites Drives C–C Coupling Activity in Rare Earth–Cu CO 2 Reduction Catalysts · 2026 · DOIElectrochemical CO 2 reduction (eCO 2 RR) is increasingly capable of delivering downstream‐compatible carbon products, yet the interfacial origin of pathway selection remains insufficiently understood.
Coordination‐Engineered Interfacial Pathway Partitioning for Electrocatalytic CO 2 Conversion and Downstream Upgrading · 2026 · DOIThe need to avoid exposing sites that favor methane or methanol at higher rates.
Thermal and Photocatalytic Conversion of CO 2 to Ethanol: Advances in Catalyst Design, Challenges, and Opportunities · 2026 · DOIChallenges remain in achieving high selectivity and kinetics in neutral electrolytes. The process is kinetically hindered by the high C=O bond energy (~806 kJ mol -1).
Enhanced CO2 Electroreduction to CO in Neutral Electrolytes via Sn-Doped Copper Catalysts · 2026 · DOIThe electrosynthesis of methane is hindered by demanding multi-electron kinetics and mass-transport constraints. Prior studies have not established a clear structure-mass transfer-reactivity relationship for Cu TPEs.
Highly Efficient Methane Electrosynthesis Enabled by Precise, Multifaceted Interface Regulation · 2026 · DOIThe need to stabilize the electrochemical environment and preserve the DSA anode during operation. The challenge of promoting selective bromide-mediated epoxidation. The importance of controlling the bromine speciation in the system.
Further studies on the scalability and stability of the In-BDC catalyst. Investigations into the application of In-MOFs for other electrochemical reduction reactions.
Indium-based Metal Organic Frameworks (In-MOFs) for Electrochemical Reduction of Carbon Dioxide to Formate · 2026 · DOIImproving electrolyzer technology to enhance CO2 conversion rates, - Reducing electricity costs through the development and widespread adoption of renewable energy sources, - Enhancing the Faraday efficiency of the reduction…
Techno-Economic Assessment of Electrochemical CO2 Reduction to Ethylene: A Cu10–Sn Catalyst Case Study and Performance Targets · 2026 · DOIAchieving higher yields, improved selectivity, and long-term stability in renewable ethanol production from captured CO2 - Identifying key challenges and future directions for CO2-to-ethanol conversion - Developing catalysts with enhanced ethanol selectivity…
Thermal and Photocatalytic Conversion of CO 2 to Ethanol: Advances in Catalyst Design, Challenges, and Opportunities · 2026 · DOIThe resulting catalyst delivers efficient alkaline HER and, importantly, sustains hydrogen evolution deep into the high‐current‐density regime with strong operational durability, addressing a key limitation of many PtNi‐based catalysts commonly evaluated only at low currents.
One‐pot synthesis of PtNi /carbon composites derived from polytetrahydrofuran for bifunctional alkaline HER and ORR · 2026 · DOIFurther optimization of the interposer design and operating protocol, - Investigation of other ionomers and their effects on CO2 capture efficiency, - Scaling up the system for industrial…
Electrochemical direct air capture by local alkalinity generation at three-dimensional interfaces · 2026 · DOIFurther investigation of the electrocatalytic CO2 reduction reaction using the optimized rGONafion-Cu-60 + 60 µL electrode. Exploration of the potential applications of the electrocatalytic CO2 reduction reaction in renewable energy conversion and storage systems.
Nafion fluorine-modified rGO-modified Cu electrode for efficient electrocatalytic CO2 reduction · 2026 · DOI
Most-cited papers in CO2 Reduction Techniques and Catalysts
- What would it take for renewably powered electrosynthesis to displace petrochemical processes? · Science · 2019 · 2,860 citations
- Accelerated discovery of CO2 electrocatalysts using active machine learning · Nature · 2020 · 1,532 citations
- CO 2 electrolysis to multicarbon products at activities greater than 1 A cm −2 · Science · 2020 · 1,526 citations
- Electrocatalytic reduction of CO2 to ethylene and ethanol through hydrogen-assisted C–C coupling over fluorine-modified copper · Nature Catalysis · 2020 · 1,482 citations
- CO 2 electrolysis to multicarbon products in strong acid · Science · 2021 · 1,361 citations
- Coupling N2 and CO2 in H2O to synthesize urea under ambient conditions · Nature Chemistry · 2020 · 1,088 citations
- Advances and Challenges for the Electrochemical Reduction of CO 2 to CO: From Fundamentals to Industrialization · Angewandte Chemie International Edition · 2021 · 1,031 citations
- Absence of CO2 electroreduction on copper, gold and silver electrodes without metal cations in solution · Nature Catalysis · 2021 · 993 citations
- Operando studies reveal active Cu nanograins for CO2 electroreduction · Nature · 2023 · 811 citations
- The role of in situ generated morphological motifs and Cu(i) species in C2+ product selectivity during CO2 pulsed electroreduction · Nature Energy · 2020 · 770 citations
Most recent work
- Nitrogen-doped carbon layer thickness modulates the Cu 0 /Cu + interface for selective and stable CO 2 electroreduction to ethylene · Chemical Communications · 2026
- Decoupling Product Selectivity in Electrocatalytic CO 2 Reduction by Steering the Interfacial Water Structure · Journal of the American Chemical Society · 2026
- Janus Mn single atoms for triggering efficient photothermal catalytic CO 2 methanation through spin polarization effect · Science Advances · 2026
- Activating Bismuth Nanosheets for Electrochemical CO 2 Reduction by Strain Engineering · Small · 2026
- Advances in electrochemical synthesis of urea from CO 2 and nitrogen-containing precursors · Chemical Communications · 2026
- Emerging roles of cations in electrocatalytic reduction of CO2 and CO · Nature Energy · 2026
- Synergizing Defect Chemistry and Single‐Atom Catalysis: A Mechanistic Approach Toward Photochemical and Electrochemical CO 2 RR Applications · Advanced Energy Materials · 2026
- MOF-derived doped porous carbon-based catalysts for CO 2 electroreduction: design, mechanisms, and scale-up · Materials Chemistry Frontiers · 2026
- Construction of solid-iodine-regulated Cu2O-Cu (200) heterointerface electrocatalyst for enhancing the CO2RR to ethylene by promoting the asymmetric · Applied Catalysis B: Environmental · 2026
- Engineering Multiple Active Site Architectures for Advanced Electrocatalytic Conversions · Advanced Energy Materials · 2026
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